Dear Mervin, Steve, George, James and Casper,
(1) Thermodynamics studies real physical systems, which are always open for energy flows or flows of matter. Therefore the laws of Thermodynamics hold for open systems. As a consequence, the information at the common-questions section of Biologos “The second law is only valid in closed systems with no external sources of energy. Since the Earth receives continual energy from the Sun, the second law does not apply”, is incorrect and needs adjustment.
(2) The 2nd Law is based on two fundamental characteristics of our physical reality: (A) the energy supplied to a system can never be extracted from it completely in the form of work done by the system on its surroundings, and (B) a system can never be brought to a higher energy level without doing work on the system. The empirical principles denoted as A and B are known as Kelvin’s principle and Clausius’ principle, respectively. In Thermodynamics, both principles are combined into one principle, which is known as the second law of Thermodynamics. It has the shape of a mathematical calculable formula thanks to the use of the concept of ‘entropy’ as a measure for the disorder of a system:
Circular-Integral dQ/T < S2 – S1
The left term of the formula describes the supply of energy over the boundaries of a system when moving from state 1 to state 2, during a time interval (t1, t2). The right term describes the decrease of the entropy of the system. Using Bolzman’s law, S = k Ln W (W is the probability of the state of a system) the entropy S1 of the system at t1, respectively the entropy S2 of the system at t2, can be calculated.
(3) The 2nd law indicates that a system can only move towards a less probable state (i.e., a state of higher order/less disorder) if energy is supplied to the system from the outside. This corresponds to the principle of Clausius. The second law also indicates that not all supplied energy can be transformed into a reduction of the disorder/entropy, but that always some entropy-reduction is lost. This corresponds to the principle of Kelvin. The second law thus expresses the same properties of physical reality as the principles of Kelvin and Clausius do.
(4) The principles of Kelvin and Clausius are beyond discussion. They hold for open systems and also hold locally for a subsystem somewhere within a system. As the 2nd Law is grounded in the principles of Kelvin and Clausius, the 2nd Law cannot be put aside by claiming that the 2nd Law is not applicable for open systems, or by claiming that for a subsystem the 2nd Law would not apply.
(5) The principles of Kelvin and Clausius, as well as the 2nd Law, indicate that if the sum of the incoming and outgoing energy flows is zero, the entropy of a system will increase, and sooner or later it will move towards its most probable state of maximal entropy.
(6) The principles of Kelvin and Clausius and the 2nd Law capture a fundamental characteristic of out physical reality: continual work and effort are needed to sustain order or to turn chaos into order. If continual work and effort is absent, as in natural processes (which are opposed to industrial processes) order will ultimately turn into maximal disorder. Anyone who tries to deny this fundamental characteristic of our physical reality comes in conflict with empirical science and the empirical facts in which empirical science is grounded.
(7) It may be suggested that locally disorder can decrease ever further if elsewhere in the system disorder increases. I have disproved this theory mathematically in point 3 of my post on January 14. This falsification can be illustrated using to the test facility I described in point 2 of the same post. The theory that somewhere on the rock molecules start ordering themselves while somewhere else on the rock molecules start to fall apart in a even higher degree, means that a ‘rock-battery’ is emerging, in which differences in energy level increase ever further. The evolution of such a ‘rock battery’ can only happen in the fantasy world of the Flintstones; not in the real world.
(8) Indeed new stars and galaxies are born in the universe. But ultimately they will fall apart, and turn into their most probable state, and move towards the lowest energy level. Indeed natural processes as lightning, wind, rain, heating, cooling, radiation, tectonic forces, etcetera, can turn simple molecules into complex molecules. But sooner or later they will fall apart; the larger the molecules that are formed, the sooner. This can be illustrated by a tennis ball that falls from a table. It will bounce upwards a number of times, despite gravity. But the height of the bounces will decrease ever further. Sooner or later the ball will reach its lowest energy level and most probable state, and stays motionless on the ground. After ten or hundred of years, the molecules in the ball will disintegrate into simple molecules, and the ball turns into dust. And after thousands or millions of years, the dust will spread over the cooling down universe.
(9) The test facility mentioned in point 2 of my post on 14 January is rather simple. In 1953, PhD student Stanley Miller has built a more sophisticated one. He set out to prove that natural processes can transform basic organic substances into amino acids in an ever higher concentration. To this end, he took a glass flask with two inwardly projecting electrodes between which he could make sparks stagger and filled the flask with water, methane, ammonia and carbon dioxide. Indeed he found that the artificial lightning in his simulation of a primitive earth atmosphere could produce amino acids. But he also found that the concentration of building blocks in the flask did not increase ever further, because new sparks destroyed the building blocks that were initially formed; the larger the faster. Instead of reporting that natural processes are not able to produce an ever concentrated primordial soup, he attached a transport mechanism to the lightning flask, to transfer the building blocks that were produced to a second flask where they would be safe for destruction. In fact, Miller built a primitive amino acid factory, with which he succeeded to produce an ever more concentrated ‘primordial soup’. Miller claimed his adjusted test set proved that natural processes could have produced billions of tons of building blocks for life in the primordial oceans. Instead, Miller’s experiments prove that an ever more concentrated soup of amino acids can not arise by natural processes, but demands the building of a factory.
(10) Based on the false claims of Miller and his supervisors, its it broadly believed today that organic molecules possess an intrinsic, hidden desire to organize themselves into increasingly larger structures. This view on matter is a repetition of the Alchemist’s view, who believed that matter does not merely consist of four basic elements (water, fire, air and earth) but also contains a hidden force (the ‘quint essence’). Many people believe that if we search long enough, this hidden force will be discovered and after triggering it in the right way, it can be released, resulting into a natural process in which organic molecules will transform themselves into increasingly larger and more complex structures. As a consequence, energy would become available for free and the chemical industry would become useless.